Product ID:CAUSTIC SPILL EMERGENCY CLEANUP KIT
MSDS Date:04/17/1987
FSC:6850
NIIN:00N082317
MSDS Number: CGCRN

MALLINCKRODT CHEMICAL INC

PARIS, KY 40362
US

Emergency Phone: 314-539-1600; 314-982-5000

Info Phone: 314-539-1600

Cage: 23104

MALLINCKRODT SPECIALTY CHEMICALS CO

PHILLIPSBURG, NJ 08865 US

Telephone: 908-859-2151

Cage: 62910

CITRIC ACID, MONOHYDRATE

CAS: 5949-29-1

RTECS: GE7810000

OSHA PEL N/K

ACGIH TLV: N/K

11700 MG/KG

CAS: 77-92-9

RTECS: GE7350000

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE RESP IRRIT AS
AN ORG ACID. INGEST: EXTREMELY LGE ORAL DOSAGES MAY PRDCE GI
DISTURB. SKIN: MAY IRRITATE SKIN, ESP IN SENSITIVE AREAS. SORENESS,
MILD INFLAMM MAY OCCUR. EYES: MIL D IRRIT. ALSO POSS TEMPORARILY
ABRASIVE. REDNESS, TEARING & PAIN MAY OCCUR. CHRONIC: NO
INFORMATION FOUND.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NO INFORMATION FOUND.

First Aid:INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION FOR
ANY BREATHING DIFFICULTY. INGESTION: GIVE SEVERAL GLASSES OF WATER
TO DRINK TO DILUTE. IF LARGE AMOUNTS WERE SWALLOWED, GET MEDICAL
ADVICE. S KIN: WASH EXPOSED AREA WITH SOAP AND WATER. GET MEDICAL
ADVICE IF IRRITATION DEVELOPS. EYES: WASH THOROUGHLY WITH RUNNING
WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ADVICE IF IRRITATION
DEVELOPS.

Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:FINE DUST DISPERSED IN AIR IN SUFFICIENT
CONCENTRATIONS, AND IN THE PRESENCE OF AN IGNITION SOURCE IS A
POTENTIAL DUST EXPLOSION HAZARD.

Spill Release Procedures:VENTILATE AREA OF LEAK/SPILL. CLEAN-UP
PERSONNEL MAY REQUIRE PROT CLOTHING & NIOSH APPROVED RESP PROT FROM
DUST. SWEEP UP & CONTAINERIZE FOR RECLAMATION/DISPOSAL. AVOID DUST
DISPERSAL. TRACE RESIDUE M AY BE FLUSHED TO SEWER W/LARGE AMOUNTS
OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER,
STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL
DAMAGE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:FOR CONDITIONS OF USE WHERE EXPOSURE TO THE DUST
IS APPARENT, A NIOSH APPROVED DUST/MIST RESPIRATOR MAY BE WORN. FOR
EMERGENCIES, A NIOSH APPROVED SCBA MAY BE NECESSARY.
Ventilation:IN GEN, DILUTION VENT IS SATISFACTORY HLTH HAZ CTL FOR THIS
SUBSTANCE. HOWEVER, IF CNDTNS OF USE CREATE (SUP DAT)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . WEAR CLEAN BODY-COVERING CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VENT: DISCOMFORT TO WORKER, LOC EXHST SHOULD BE CONSIDERED.

Boiling Pt:B.P. Text:DECOMPOSES
Melt/Freeze Pt:M.P/F.P Text:212F,100C
Solubility in Water:60 G/100 ML @ 20C
Appearance and Odor:WHITE GRANULES; ODORLESS

Stability Indicator/Materials to Avoid:YES
METAL NITRATES, ALKALI CARBONATES AND BICARBONATES.
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE
AND STORAGE.
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE MAY
FORM WHEN HEATED TO DECOMPOSITION.

Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE
DISPOSED AS HAZARDOUS WASTE IN AN APPROVED WASTE DISPOSAL FACILITY.
ENSURE COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.